Global analysis of peroxy radicals and peroxy radical-water complexation using the STOCHEM-CRI global chemistry and transport model
نویسندگان
چکیده
منابع مشابه
Peroxy radical chemistry at Mace Head, Ireland
Peroxy radical chemistry and the control of ozone photochemistry at Mace Head, Ireland during the summer of 2002 Z. L. Fleming, P. S. Monks, A. R. Rickard, D. E. Heard, W. J. Bloss, P. W. Seakins, T. J. Still, R. Sommariva, M. J. Pilling, R. Morgan, T. J. Green, N. Brough, G. P. Mills, S. A. Penkett, A. C. Lewis, J. D. Lee, A. Saiz-Lopez, and J. M. C. Plane Department of Chemistry, University o...
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Seasonal dependence of peroxy radical concentrations at a northern hemisphere marine boundary layer site during summer and winter: evidence for photochemical activity in winter Z. L. Fleming, P. S. Monks, A. R. Rickard, B. J. Bandy, N. Brough, T. J. Green, C. E. Reeves, and S. A. Penkett Department of Chemistry, University of Leicester, Leicester, UK School of Environmental Sciences, University...
متن کاملIsoprene Peroxy Radical Dynamics.
Approximately 500 Tg of 2-methyl-1,3-butadiene (isoprene) is emitted by deciduous trees each year. Isoprene oxidation in the atmosphere is initiated primarily by addition of hydroxyl radicals (OH) to C4 or C1 in a ratio 0.57 ± 0.03 (1σ) to produce two sets of distinct allylic radicals. Oxygen (O2) adds to these allylic radicals either δ (Z or E depending on whether the allylic radical is cis or...
متن کاملPeroxy radical chemistry and OH radical production during the NO3-initiated oxidation of isoprene
Peroxy radical reactions (RO2 + RO2) from the NO3-initiated oxidation of isoprene are studied with both gas chromatography and a chemical ionization mass spectrometry technique that allows for more specific speciation of products than in previous studies of this system. We find high nitrate yields (∼ 80 %), consistent with other studies. We further see evidence of significant hydroxyl radical (...
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ژورنال
عنوان ژورنال: Atmospheric Environment
سال: 2015
ISSN: 1352-2310
DOI: 10.1016/j.atmosenv.2015.02.020